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You can find a lot of info on making nice acrylic cases at case modder forums like www.gruntville.com and www.thebestcasescenario.com.


A very standard thing to do is to solvent weld acrylic using solvents sold for exactly that---solvent welding acrylic.


If your parts are cut very flat, you can butt two pieces of acrylic together, applying just a little solvent, and it will wick throughout the joint, creating an strong, invisible joint.


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